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ADP-L-glycero-D-manno-heptose + alpha-L-glycero-D-manno-heptosyl-(1->5)-[(3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->4)]-(3-deoxy-alpha-D-manno-oct-2-ulopyranosylonate)-(2->6)-2-deoxy-2-[[(3R)-3-(dodecanoyloxy)tetradecanoyl]amino]-3-O-[(3R)-3-(tetradecanoyloxy)tetradecanoyl]-4-O-phospho-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-[[(3R)-3-hydroxytetradecanoyl]amino]-1-O-phosphono-alpha-D-glucopyranose <=> ADP + heptosyl-(1,3)-heptosyl-KDO2-lipid_A
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2.4.99.B7
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–
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BRENDA:
BR51118
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palmitoleoyl-[acyl-carrier_protein] + alpha-Kdo-(2->4)-alpha-Kdo-(2->6)-lipid_IVA <=> alpha-Kdo-(2->4)-alpha-Kdo-(2->6)-(palmitoleoyl)-lipid_IVA + [acyl-carrier_protein]
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2.3.1.242
Kdo2-lipid IVA palmitoleoyltransferase
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–
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BRENDA:
BS427337
KEGG:
R10906
MetaCyc:
PALMITOTRANS-RXN
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UDP-2,3-bis((3R)-3-hydroxymyristoyl)-alpha-D-glucosamine + 2,3-bis(3-hydroxytetradecanoyl)-beta-D-glucosaminyl_1-phosphate <=> UDP + 2,3-bis(3-hydroxytetradecanoyl)-D-glucosaminyl-(beta-D-1,6-)-2,3-bis(3-hydroxytetradecanoyl)-D-glucosaminyl_beta-phosphate
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2.4.1.182
lipid-A-disaccharide synthase
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–
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BRENDA:
BS422082
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UDP-glucose + heptosyl-(1,3)-heptosyl-KDO2-lipid_A <=> UDP + glucosyl-(1,3)-heptosyl-(1,3)-heptosyl-KDO2-lipid_A
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2.4.1.B64
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–
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BRENDA:
BR51116
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UDP-2,3-bis((3R)-3-hydroxymyristoyl)-alpha-D-glucosamine + H2O <=> 2,3-bis(3-hydroxytetradecanoyl)-beta-D-glucosaminyl_1-phosphate + UMP
|
3.6.1.54
UDP-2,3-diacylglucosamine diphosphatase
|
–
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BRENDA:
BS402961
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|
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ADP-L-glycero-D-manno-heptose + Kdo2-lipid_A <=> ADP + Hep2-Kdo2-lipid_A
|
2.4.99.B7
|
–
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BRENDA:
BS436289
|
|
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(3R)-3-hydroxymyristoyl-[acyl-carrier_protein] + UDP-3-O-((3R)-3-hydroxymyristoyl)-alpha-D-glucosamine <=> UDP-2,3-bis((3R)-3-hydroxymyristoyl)-alpha-D-glucosamine + [acyl-carrier_protein] + H+
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2.3.1.191
UDP-3-O-(3-hydroxymyristoyl)glucosamine N-acyltransferase
|
–
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BRENDA:
BR49174
KEGG:
R04550
MetaCyc:
UDPHYDROXYMYRGLUCOSAMNACETYLTRANS-RXN
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|
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2,3-bis(3-hydroxytetradecanoyl)-D-glucosaminyl-(beta-D-1,6-)-2,3-bis(3-hydroxytetradecanoyl)-D-glucosaminyl_beta-phosphate + ATP <=> H+ + lipid_IVA_(E._coli) + ADP
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2.7.1.130
tetraacyldisaccharide 4'-kinase
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–
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BRENDA:
BR47743
KEGG:
R04657
MetaCyc:
TETRAACYLDISACC4KIN-RXN
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